Chemistry S3

Created by Ethan He

Elements in the periodic table are arranged in order of increasing...
Atomic number

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TermDefinition
Elements in the periodic table are arranged in order of increasing...
Atomic number
Why do elements in the same group have similar chemical properties?
Same number of outer-shell electrons
What do the seven 'diatomic elements' have in common?
They exist naturally as X₂ molecules
What charge and location does a proton have?
1+, inside nucleus
How do you calculate the number of neutrons in an atom?
Mass number − atomic number
Isotopes of the same element have the same number of protons but different...
Number of neutrons
How does a metal atom typically form an ion?
By losing electrons
Why do atoms form bonds?
To achieve a full outer shell / be more stable
A compound formed between a metal and a non-metal is...
Ionic
Compounds ending in '-ide' typically contain...
Only two elements
A covalent bond is best described as...
Mutual attraction of two nuclei for a shared pair of electrons
What shape is a water molecule (H₂O)?
Angular (bent)
Why do covalent molecular substances have low melting/boiling points?
Only weak forces between molecules need breaking
How many covalent bonds does each carbon atom form in diamond?
4
Why does graphite conduct electricity while diamond doesn't?
Graphite has delocalised electrons free to move; diamond's electrons are all used in bonds
An ionic bond is best described as...
Electrostatic attraction between a positive and negative ion
Why don't solid ionic compounds conduct electricity?
The ions are fixed in place in the lattice, not free to move
What happens when an ionic compound dissolves in water?
The lattice breaks up and ions are surrounded by water molecules, becoming free to move
A substance melts at −35°C and boils at 150°C. What state is it at room temperature (~20°C)?
Liquid
Elements in the periodic table are arranged in order of increasing what?
Atomic number
Why do elements in the same group have similar chemical properties?
They have the same number of outer-shell (valence) electrons
What are Group 1 elements called?
Alkali metals
What are Group 7 elements called?
Halogens
What are Group 0 elements called, and why are they unreactive?
Noble gases
What does the period (row) number tell you about an atom?
The number of electron shells it has
What are the "7 diatomic elements" and what do they have in common?
H2, N2, O2, F2, Cl2, Br2, I2
How does reactivity change down Group 1 (alkali metals)?
Reactivity increases down the group
What charge and mass does a proton have?
1+ charge, mass of 1
What charge and mass does a neutron have?
0 charge, mass of 1
What charge and mass does an electron have?
1- charge, negligible mass (~0)
Why are atoms overall neutral?
Because the number of protons (+) equals the number of electrons (-)
What did Rutherford's gold foil experiment show?
Atoms are mostly empty space with a small, dense, positively charged nucleus
In nuclide notation, what does the atomic number tell you?
The number of protons
In nuclide notation, what does the mass number tell you?
The total number of protons + neutrons
How do you calculate the number of neutrons in an atom?
Mass number minus atomic number
What are isotopes?
Atoms of the same element (same atomic number) with a different mass number (different number of neutrons)
Do isotopes have the same or different chemical properties?
Same chemical properties (same electron arrangement), but different physical properties (different mass)
What is an ion?
A particle that has lost or gained electrons
How do metal atoms typically form ions?
By losing electrons, forming positive ions
How do non-metal atoms typically form ions?
By gaining electrons, forming negative ions
How are electrons arranged around the nucleus?
In energy levels (shells), filled from the inside out (2, 8, 8...)
An atom has the electron arrangement 2,8,7. Which group is it in?
Group 7
Why do atoms form bonds?
To achieve a full outer shell like the noble gases — this makes them more stable / lower energy
What type of compound forms between a metal and a non-metal?
Ionic
What type of compound forms between two non-metals?
Covalent
What does a compound name ending in "-ide" tell you?
It contains only two elements (e.g. sodium chloride)
What does a compound name ending in "-ite" or "-ate" tell you?
It contains three elements, one of which is oxygen (e.g. sulfate, carbonate)
What is a covalent bond?
Two atoms held together by their shared attraction to a shared pair of electrons
What is a single covalent bond vs a double covalent bond?
Single = 1 shared pair of electrons (e.g. H-H); double = 2 shared pairs (e.g. O=O)
What is the structure of a covalent molecular substance?
Small, separate molecules held together by weak van der Waals forces between molecules
What is the structure of a covalent network substance?
One giant 3D lattice of atoms, with strong covalent bonds throughout — no separate molecules
Why do covalent molecular substances have low melting/boiling points?
Only the weak van der Waals forces between molecules need to be broken, not the strong covalent bonds within them
Why do covalent network substances have high melting/boiling points?
Many strong covalent bonds throughout the lattice must be broken
Give examples of covalent molecular substances
H2O, CO2, Cl2, CH4
Give examples of covalent network substances
Diamond, graphite, silicon, boron
How many covalent bonds does each carbon atom form in diamond, and what structure does this give?
4 bonds — a rigid 3D tetrahedral network
How many covalent bonds does each carbon atom form in graphite, and what structure does this give?
3 bonds — flat layers, with weak forces between layers letting them slide
Why does graphite conduct electricity but diamond doesn't?
Graphite has one delocalised electron per carbon free to move; diamond uses all electrons in bonds, so none are free
What determines the shape of a molecule?
The number of bonded pairs and lone pairs around the central atom (electron pairs repel and spread as far apart as possible)
What shape is a molecule with 2 bonded pairs and no lone pairs (e.g. HCl)?
Linear
What shape is a molecule with 2 bonded pairs and 2 lone pairs (e.g. H2O)?
Angular (bent) — lone pairs repel more, giving a smaller bond angle
What shape is a molecule with 3 bonded pairs and 1 lone pair (e.g. NH3)?
Trigonal pyramidal
What shape is a molecule with 4 bonded pairs and no lone pairs (e.g. CH4)?
Tetrahedral
How can you predict molecule shape using group numbers?
Compare the central atom's group to a known example — e.g. S is in the same group as O, so H2S is angular like H2O
If melting point is above room temperature, what state is the substance at room temperature?
Solid
If melting point is below room temperature but boiling point is above it, what state is the substance at room temperature?
Liquid
If both melting point and boiling point are below room temperature, what state is the substance at room temperature?
Gas
What is an ionic bond?
The electrostatic attraction between a positive ion and a negative ion
How is an ionic bond formed?
By the transfer of electrons from a metal atom to a non-metal atom
What is the structure of an ionic compound?
A giant ionic lattice — a regular 3D pattern of alternating positive and negative ions
Why do ionic compounds have high melting and boiling points?
There are many strong ionic bonds (electrostatic forces) throughout the lattice that need to be broken
Do solid ionic compounds conduct electricity? Why or why not?
No — the ions are fixed in place in the lattice and not free to move
Do molten or dissolved ionic compounds conduct electricity? Why?
Yes — the lattice breaks down and the ions are free to move
What happens when an ionic compound dissolves in water?
The lattice breaks apart and water molecules surround and separate the ions
Do covalent molecular substances (like H2O, CO2) conduct electricity as solids or liquids?
No — no free ions or delocalised electrons
Does graphite conduct electricity as a solid?
Yes — due to delocalised electrons (the exception among covalent substances)
Do metals conduct electricity as solids and liquids?
Yes, in both states — delocalised electrons are always free to move
What is a metallic bond?
A lattice of positive ions surrounded by a "sea" of delocalised electrons, held by electrostatic attraction
Why do metals conduct electricity?
They have delocalised electrons that are free to move and carry charge
Why are metals malleable and ductile?
The layers of positive ions can slide over each other while staying held by the sea of delocalised electrons
What's the difference between atomic number and mass number?
Atomic number = number of protons; mass number = number of protons + neutrons
What's an easy way to remember why ionic compounds only conduct when molten/dissolved, not solid?
Solid = ions locked in lattice, can't move; molten/dissolved = lattice breaks, ions move freely